Solvation Structure of the Ti(III) Ion in Methanol Solutions and in Perfluorinated Ionomers Swollen by Water and Methanol. A Study by ESR and ENDOR
نویسنده
چکیده
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namensnennung 4.0 Lizenz. Solvation Structure of the Ti(III) Ion in Methanol Solutions and in Perfluorinated Ionomers Swollen by Water and Methanol. A Study by ESR and ENDOR
منابع مشابه
Thermodynamic study of ion- association in KNO3 solution in the mixed solvent (water +methanol)
The solubility of KNO3 in the mixed solvent (water 85%+methanol 15%) were determined by using solvent evaporating method at different temperatures (25, 30, 40, 50, 60 ;C). In addition the equilibrium constant of ion pair formation, KIP, for K+NO3 – ion-pair on the basis of Fuoss contact ion pair model was calculated. Upon choosing the extended Debye-Hückel model for estimating the mean activity...
متن کاملThermodynamics of Ion Association in the Saturated Solution of The Mixed Solvent (methanol+water) and Ion Pairing at 25.0°C
In this study, the ion association phenomenon in the saturated solution of KCl in the mixed solvent(methanol+water) was studied. The solubility of this compound in the mixed solvent (methanol+water by value percent of methanol = 60%), and in the presence of various molarities of NaNO3 wasdetermined by the solvent evaporation method at 25.0°C. The results enable us to estimate the valueof thermo...
متن کاملSynthesis of Sulfonated Polystyrene/acrylate–ionic Liquid (Si-SPS/A–IL) Hybrid Membranes for Methanol Fuel Cells
In this paper, the silicon-containing sulfonated polystyrene/acrylate–ionic liquid (Si-SPS/A–IL)hybrid membranes was prepared to obtain the proton exchange membrane (PEM) materials withhigh methanol barrier and good selectivity. The Si-SPS/A–IL hybrid membranes characterized asthe function of IL to evaluate their potential as PEMs in direct methanol fuel cells (DMFCs).Fourdifferent Hybrid mater...
متن کاملSolvation Phenomena of Potassium Thiocyanate in Methanol–Water Mixtures
This paper reports the results of a variety of experiments carried out for understanding the solvation behavior of potassium thiocyanate in methanol–water mixtures. Electrical conductivity, speed of sound, viscosity, and FT-Raman spectra of potassium thiocyanate solutions in 5 and 10% methanol–water (w/w) mixtures were measured as functions of concentration and temperature. The conductivity and...
متن کاملEnergy Study at Different Temperatures for Active Site of Azurin in Water, Ethanol, Methanol and Gas Phase by Monte Carlo Simulations
The interaction between the solute and the solsent molecules play a crucial role in understanding the various molecular processes involved in chemistry and biochemistry, so in this work the potential energy of active site of azurin have been calculated in solvent by the Monte Carlo simulation. In this paper we present quantitative results of Monte Carlo calculations of potential energies of ...
متن کامل